期刊信息

  • 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
  • 主办： 河北师范大学
  • ISSN： 1000-5854
  • CN： 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

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CH3N和CH2NH及其系列氧化物的研究现状

  • 1. 华北电力大学科技学院, 河北保定　071003;
    2. 河北工业职业技术学院环境与化学工程系, 河北石家庄　050091;
    3. 河北师范大学计算量子化学研究所, 河北石家庄　050016
  • DOI：

Current Status of the Studies on CH3N and CH2NH and Their Seires of Oxides

摘要/Abstract

摘要：

含氮化合物与对流层的光化学现象有密切关系,鉴于含氮化合物的研究成果对于改善大气环境有很重要的现实意义,笔者主要分3个方面概述了CH3N和CH2NH及其系列氧化物目前的研究现状,并展望了含氮化合物的研究前景.

Abstract：

The experimental and theoretical investig ations concerning the properties and reactions of nitrogen containing compounds have been carried out extensively for the important role they play in photochemistry. The studies on nitrogen containing compounds are int roduced from the following three aspects for their realistic significance in atmosphere environment. The prospect of studies on nitrogen containing compounds is, also anticipated

关键词

关键词： 含氮化合物 ; CH3N ; CH3NO ; CH3NO2 ; 研究前景
Key words： nitrogen containing compounds ; CH3N ; CH3NO ; CH3NO2 ; prospect of research

参考文献 39

  • [1] ISOBEL C W, MALCOLM A D, FLUENDY.Spectroscopy and Dy namics of Ntrome thane (CH3NO2)and Is Anionic States [J]. Int J Mass Spectrom, 2001, 205 :71-82.
  • [2] WINCEL H. Gas-phase Clustering Reactions of NO2-, C2H3NO2-, C2H4NO2-, C2H5NO2- and C2H5NO4- with C2H5NO2 [J]. Int J Mass Spect, 2004, 232 :185-194.
  • [3] KEMNITZ C R, ELLISON G B, KARNEY W L. CASSCF and CASPT2 Ab Initio Electronic Structure Calculations Find Sing let Methylnitrene Is an Energy Minimum [J]. J Am Chem Soc, 2000, 122(6):1098-1101.
  • [4] HU Wen-fang, HE Tian-jing, CHEN Dong-ming, et al.Theoretical Study of the CH3NO2 Unimolecular Decomposition Potential Energy Surface [J]. J Phys Chem A, 2002, 106:7294-7303.
  • [5] SUN Zheng, ZHENG Shi-jun, MENG Ling-peng, et al.HeI Pho toelectron Spectroscopy of the Isoproxy (CH3)2CHO Radical [J]. Chem Phy s Lett, 2003, 369:180-183.
  • [6] DEMUYNCK J, FOX D J, YAMAGUCHI Y, et al.Triplet Methy lnitrene :An Indefinitely Stable Species in the Absence of Collisions [J]. J Am Chem Soc, 1980, 102(20):6205-6207.
  • [7] ALEXEY T, NIZAMOY B, PAUL J. The Electronic Spectrum of Methyleneimine [J]. J Phy s Chem, 2004, 108 :4433-4439.
  • [8] TRAVERS M J, COWLES D C, CLIFFORD E P, et al.Photoelectron Spectroscopy of the CH3N- Ion [J]. J Chem Phys, 1999, 111 :5349-5360.
  • [9] SHANG Hai-rong, GAO Ruo-mu, YING Li-ming, et al. Laser I nduced Dispersed Fluorescence Spectra of CH3N Radical and the Lifetime of Its A3E State [J]. Chem Phys Lett, 1997, 267:345-350.
  • [10] SHANG Hai-rong, YING Li-ming, ZHAO Xin-sheng, et al.I nvestigation of the AE※XA System of Methy lnitrene Radical by Laser Spectroscopy [J]. J Chem Phys, 1995, 103(11):4418-4426.
  • [11] RICHARDS C, MEREDITH C, KIM S J.Is There A Potential Minimum Cor responding To Singlet Methy lnitrene ? A Study of the CH3N To CH2NH Rearrangement on the Low est Singlet State Potential Energy Hypersurface [J]. J Chem Phy s, 1994, 100 :481-496.
  • [12] DICKENS J E, IRVINE W M. The Formaldehyde Or tho/para Ra tio As a Probe of Dar k Cloud Chemistry and Ev olutio n [J]. J Astrophy s, 1999, 518:733-739.
  • [13] GODFREY P D, BROWN R D, CLERK F O, e t al.DetectionofInterstellar HN13C [J]. Nature, 1976, 262(5570):672-674.
  • [14] 杨丽娟, 孟令鹏, 曾艳丽, 等.CH2NH 与O(3P)反应的量子化学及电子密度拓扑分析研究[J]. 物理化学学报, 2007, 23: 311-316.
  • [15] THOMASSY F A, LAMPE F W. A Mass Spectrometric Study of the Dimerization of Nitrosomethane [J]. J Phys Chem, 1970, 74(6):1188-1193.
  • [16] FROST D C, LAU W M, MCDOWELLl C A, et al.A Study by Helium(HeI)Photoelectron Spectroscopy of Monomeric Nitrosomethane, the Cis and Trans Dimers, and Formaldox ime [J]. J Phys Chem, 1982, 86 :3577-3581.
  • [17] CHONG D P,WESTWOOD N P C.Methyl- and Dimethylketene :He I Photoelectron Spectra and Vertical Ionization Potentials Calculated by Using Perturbation Corrections to Koopmans' Theorem [J]. J Phys Chem, 1984, 88 :1479-1481.
  • [18] CHESWORTH A G, HASZELDINE R N, TAIT P J.Polymerization of Viny l Chloride by Use of Modified Ziegler-Natta Cataly sts I :Overall Kinetic Features [J]. Polymer Chemistry Edition, 1974, 12(8):1703-1716.
  • [19] BATT L, MILNE R T Int.The CH3-NO Bond Disso ciation Energy [J]. Chem Kinet, 1973, 5 :1067-1069.
  • [20] BENSON S W, CRUICKSHANK F R, GOLDEN D M, et al. Additivity Rules for the Estimation of Thermochemical Properties [J]. Chem Rev, 1969, 69 :279-324.
  • [21] VLADIMIROFF T. An Ab Initio and Density Functional Study of Nitrosomethane and Its Rear rangement Products Formaldo nitro ne and Formaldox ime [J]. J Mol Struct(Theochem), 1997, 401:141-150.
  • [22] GOWENLOCK B G, BATT L.The Isomerization of Nitrosomethane to Formaldoxime [J]. J Mol Struct (Theochem), 1998, 454 :103-104.
  • [23] SAM UELSA A C, JENSENA J O, KRISHNANB P N.Theoretical Study of the Possible Isomers and High-energy Interrnediates of HCN-H2O Complex es [J]. J Mol Struct(Themhem), 1998, 427 :199-209.
  • [24] TAYLOR W D, ALLSYON T D, MOSCATO M J, et al.Atmospheric Photodissociation Lifetimes for Nitromethane, Methyl Nitrite, and Methyl Nitrate [J]. Int J Chem Kinet, 1980, 12 :231-240.
  • [25] HEPBURN J W, BUSS R J, BUTER L J, et al.Molecular Beam Sudy of the Photochemistry of S1 Glyoxal [J]. J Phy s Chem, 1983, 87(19):3638-3641.
  • [26] PARK M S, JUNG K H, UPADHYAYA H P, et al. The Dy namicsof Oxyg en Atom Formation in the UV Photodissociation of Nitromethane [J]. J Chem Phy, 2001, 270:133-139.
  • [27] WODTKE A M, HINTSN E J, LEE Y T. Infrared Multiphoton Dissociation of Three Nitro alkanes [J]. J Phys Chem, 1986, 90:3549-3558.
  • [28] ZABARNICK S, FLEM ING J W, LIN M C. Kinetics of CH Radical Reactions with N20, SO2, OCS, CS2, and SF6[J]. Int J Chem Kinet, 1989, 21(9):765-774.
  • [29] HONDA K H, M IKUNNI M. T.The Mercury-photo sensitized Reaction of Tetrahydrothiophene-1, 1-dio xide (sulfolane)[J]. J Photochem, 1974, 3 :199-213.
  • [30] NAGAKURA S, KOJIMA M, MARUYAMA Y.Electronic Spectra and Electronic Sructures of Nitrobenzene and Nitromesitylene [J]. J Mol Spectrosc, 1964, 13 :174-192.
  • [31] KENNETH S, PITZER, GWINN W D.Nitromethane :The Heat Capacity of the Gas, the Vapor Density, and the Barrier to Internal Rotation [J]. J Am Chem Soc, 1941, 63(12):3313-3316.
  • [32] BODENBINER M, ULIC S E, WILLNER H. A Gas-phase and Matrix Isolation Study of the Equilibrium CH3ONO (Cis)and CH3ONO (Trans)by FTIR Spectroscopy [J]. J Phys Chem, 1994, 98 :6441-6444.
  • [33] CHAUVEL J P, NANCY S Jr, TRUE E.Phase Effects on Conformational Equilibriums:Nuclear Magnetic Resonance Studies of Methy l Nitrite [J]. J Phy s Chem, 1983, 87:1622-1625.
  • [34] LISA M G, CLAY D M, THOMAS A B.Rotationally Resolved Spectroscopy of the v8 Band of Cis-methyl Nitrite [J]. J Mol Spectrosc, 2004, 225 :182-188.
  • [35] 庞先勇, 张绍文.CH3O 与NO 在单、三态势能面上的反应机理[J]. 结构化学, 1996, 15(6):466-468.
  • [36] GENNADY L, GUTSEV, PURU J. Thermody namical Stability of CH3ONO and CH3ONO- A Coupled-cluster and Hartree- Fock-density-functional-theory Study [J]. J Chem Phys, 1999, 110 :403-411.
  • [37] ARENAS J F, CENTENO S P, L PEZ-TOC N I, et al.DFT and CASPT2 Study of Two Thermal Reactions of Nitromethane :C-N Bo nd Ceav ag e and Nitro-to-nitrite Isomerization :An Example of the Inverse Symmetry Breaking Deficiency in Density Functional Calculatio ns of an Homoly tic Dissociation [J]. J Mol Stru (Theochem), 2003, 630 :17-23.
  • [38] BROOKS P R, HARLAND P W, REDDEN C E. Electron Transfer from Sodium to Oriented Nitromethane, CH3NO2:Probing the Spatial Extent of Unoccupied Orbitals [J]. J Am Chem Soc, 2006, 128 :4773-4778.
  • [39] BROOKS P R, HARLAND P W, REDDEN C E.Steric Asymmetry in Electron Transfer from Potassium Atoms to Oriented Nitromethane (CH3NO2)Molecules [J]. J Phy s Chem A, 2006, 110:4697-4701.

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