期刊信息

  • 刊名: 河北师范大学学报(自然科学版)Journal of Hebei Normal University (Natural Science)
  • 主办: 河北师范大学
  • ISSN: 1000-5854
  • CN: 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

乳化法常压合成硫氰酸铵

  • 1. 河北经贸管理干部学院 教务处, 河北 石家庄 050021;
    2. 河北广播电视大学 理工部, 河北 石家庄 050071
  • DOI:

The Synthesis of Ammonium Thiocyanate by Emulsifying at the Ordinary Pressure

摘要/Abstract

摘要:

通过对以二硫化碳和氨水为原料常压合成硫氰酸铵系统单个乳化剂和复合乳化剂对反应时间产生的影响的实验室研究, 确定了复合乳化剂的最佳组成:OP-741.2%, EL-2017.6%, S-2041.2%.用乳化新工艺常压合成硫氰酸铵与不用乳化剂相比, 可使平均反应时间下降72.7%, 同时使平均收率提高7.5%.

Abstract:

This paper studied mainly the effects of a single emulsifier and complex emulsifiers on the reaction time during the synthesis of anmonium thiocyanate from CS2 and NH3 at the ordinary pressure. The best compositon of complex emulsifier has been determined: OP-741.2%, EL-20 17.6%, S-20 41.2%. By means of this method, the reaction time can be shortened by 72. 7% compared with no emuL-sifier, and the yield will be raised by 7.5%.