期刊信息

  • 刊名: 河北师范大学学报(自然科学版)Journal of Hebei Normal University (Natural Science)
  • 主办: 河北师范大学
  • ISSN: 1000-5854
  • CN: 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

水溶液中金属铜诱发芳香醛酮的烯丙基化反应

  • 1. 廊坊师范学院化学系, 河北廊坊065000;
    2. 北京矿冶研究总院, 北京100044
  • DOI:

Allylation Reactions of Aromatic Aldehydes and Ketones with Copper in Aqueous Media

摘要/Abstract

摘要:

在Cu-SnCl2-H2O体系中,超声辐射下烯丙基溴与一系列芳香醛酮进行反应,室温1∼1.5 h,得83%∼96%的烯丙基化产物.该方法时间短、产率高、对环境友好.

Abstract:

The allylation reactions of aromatic aldehydes and ketones with allyl bromide were carried out in 83%∼96% yield with Cu-SnCl2-H2O under ultrasound irradiation at room temperature for 1∼1.5h.The main advantages of the present procedure are shorter:reaction time,the higher yield and the environmentally benign way.