期刊信息
- 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
- 主办： 河北师范大学
- ISSN： 1000-5854
- CN： 13-1061/N
- 中国科技核心期刊
- 中国期刊方阵入选期刊
- 中国高校优秀科技期刊
- 华北优秀期刊
- 河北省优秀科技期刊
配合物Eu(NO3)3(phen)2的晶体结构和性质
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1. 河北师范大学化学与材料科学学院, 河北石家庄050016;
2. 河北师范大学实验中心, 河北石家庄050016 -
DOI：
Crystal Structure and Properties of Ternary Europium Complex Eu(NO3)3(phen)2
摘要/Abstract
通过X射线单晶衍射测试了配合物Eu(NO3)3(phen)2的晶体结构(phen=1,10-邻菲啉).该配合物以单核分子形式存在,中心离子Eu(Ⅲ)分别与硝酸根上的氧原子和1,10-邻菲啉上的氮原子以双齿螯合方式配位,配位数为10.荧光光谱表明该配合物有Eu(Ⅲ)的特征发射光谱,其中5D0→7F2(615nm)跃迁发射强度最高.该配合物具有良好的热稳定性.
A europium ternary complex Eu(NO3)3(phen)2( phen=1,10-phenanthroline) has been sy nthesized and it's structure has been determined by single-crystal X-ray diff raction.The title complex is mononuclear molecule.The cent ral Eu(Ⅲ) ion is connected with sixox ygen atoms of three nitrate anions and with four nit rogen atoms of two1,10-phenanthroline molecules through the mode of chelating bidentate.The coordination number of the center Eu(Ⅲ) ion is ten.Luminescence spectra of the title complex indicate that the emission peak of 615nm is the most intensive.Thermal decomposition indicates that the complex has fine thermal stability.