期刊信息

  • 刊名: 河北师范大学学报(自然科学版)Journal of Hebei Normal University (Natural Science)
  • 主办: 河北师范大学
  • ISSN: 1000-5854
  • CN: 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

石家庄市冬季降雪化学成分及其不溶物颗粒形态特征

  • 1. 河北师范大学资源与环境科学学院, 河北石家庄 050016;
    2. 河北师范大学实验中心, 河北石家庄 050016
  • DOI:

Chemical Characteristics and Insoluble Particulates. Surface Morphology of Winter Snow in Shijiazhuang City

摘要/Abstract

摘要:

选择大气环境污染严重的石家庄市冬季降雪样品,进行可溶性离子组成测试和不溶性颗粒物形态分析.结果表明,石家庄市大气降雪中离子总浓度很高,降水水质受到严重污染.降雪阴离子中以SO42-为主,NO3-较少,反映大气环境主要受燃烧排放的污染,酸性沉降的前体物较多.阳离子中以NH4+和Ca2+为主,主要来自石家庄市的土壤风沙扬尘作用.石家庄市大气降雪的(ρ(NH4+)+ρ(Ca2+))/(ρ(SO42-)+ρ(NO3-))比值高达1.93,具有对酸的强中和能力,致使其酸性降水实际发生率较低.电镜观察显示降雪中不溶物的颗粒形态特征主要有5类,其中以团聚体形态颗粒物最多,次为较规则体和球体颗粒,生物质颗粒和未知颗粒稀少,反映石家庄市冬季大气环境中悬浮颗粒物来自燃料燃烧和裸地起尘.

Abstract:

By dry or wet deposit process, pollutants in atmosphere can be transported into earth's surface environment to influence soil-plant system and water quality . Therefore study on characteristics of deposit from atmosphere is believed important for such inf luence function. For severe air pollution situat ion,Shijiazhuang city was chosen to detect its wet deposit status. Though located in the control area of SO2 in China, Shijiazhuang city has not been suffered acid rain influence. To probe into the reasons, this research collected winter snow samples to detect chemical components. The results show that the general ion concentrat ion in the samples is rather high. The major anions in the samples are SO42- and HCO3- , NO3- is nonsignificant . The major cat ions in the samples are NH4+and Ca2+, which were carried into the air by raising dust .The high ratio of (ρ(NH4+)+ρ(Ca2+))/(ρ(SO42-)+ρ(NO3-))with the value 1. 93 is thought to be the main reason for the restraining of acid precipitation forming revealing strong antacid ability of the atmospheric environment . Morphology analyse conducted under scan elect ron microscope demonst rates cong lomeration and sphere coming from burning process are in the majority of insoluble part iculates in snow samples, follow ed by sem-i regular-minera-l granule. Snow w ashing brings these suspended part iculates down to the soil and water from air.