期刊信息
- 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
- 主办： 河北师范大学
- ISSN： 1000-5854
- CN： 13-1061/N
- 中国科技核心期刊
- 中国期刊方阵入选期刊
- 中国高校优秀科技期刊
- 华北优秀期刊
- 河北省优秀科技期刊
The Design of Chiral Phase-transfer Catalyst and Comparison of Their Asymmetric Catalytic Capability
摘要/Abstract
摘要：
介绍了近几年设计的手性相转移催化剂,包括手性季铵盐、季铵盐、手性冠醚、金属配合物等,并以二苯亚胺甘氨酸叔丁酯的不对称烷基化反应为模板,对它们的催化性能进行了比较.
Abstract：
The research progress in the area of newly designed chiral phase-transfer catalysis such as chiral quaternary ammonium,chiral quaternary phosphonium,chiral crow ether and chiral salen complexes was reviewed.Their asymmetric catalytic capability was compared based on the enantioselective alkylation of N-(diphenylmethylene)glycine tert-butyl ester.