期刊信息
- 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
- 主办： 河北师范大学
- ISSN： 1000-5854
- CN： 13-1061/N
- 中国科技核心期刊
- 中国期刊方阵入选期刊
- 中国高校优秀科技期刊
- 华北优秀期刊
- 河北省优秀科技期刊
Synthesis and Spectral Properties of Chlorophenylporphyrins Amino-acid and Their Zinc Complexes
摘要/Abstract
摘要：
为了探索氯的空间位置及不同的氨基酸对卟啉-氨基酸化合物性能的影响,合成了氯代苯基酪氨酸卟啉化合物和氯代苯基组氨酸卟啉化合物等6种新型的尾式卟啉-氨基酸化合物及其锌配合物,用元素分析、紫外-可见光谱确证了其结构,并研究了氯代苯基在苯环上的不同位置时卟啉化合物光谱性质的变化.
Abstract：
In order to research the influence of different positions of chloro and the difference of amino acid on the porphyrin's properties,six new tailed-porphyrin compounds were synthesized:5-[4-(3-tyrosineylpororoxy)pheny]-10,15,20-tri(2,3 and 4 chlorphenyl) porphyrins and 5-[4-(3-histidineylproroxy)phenyl]-10,15,20-tri(2,3 and 4 chlorphenyl) porphyrins and their zinc complexes.Their structures were characterized by UV-VIS.In addition,the change of these compounds' spectral properties were studied.
关键词
Key words：
chlorophenylporphyrins
;
amino-acid
;
spectral
;
synthesis