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  • 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
  • 主办： 河北师范大学
  • ISSN： 1000-5854
  • CN： 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

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基于MnO₂溶解/沉积反应的水系电池研究进展

  • 东北大学秦皇岛分校 资源与材料学院，河北省电介质与电解质功能材料重点实验室，河北 秦皇岛 066004
  • DOI： 10.13763/j.cnki.jhebnu.nse.202603004

Research Progress on Aqueous Batteries Based on MnO₂ Dissolution/deposition Reactions

摘要/Abstract

摘要：

作为电池中的关键组成部分，MnO₂凭借其低成本、高安全性及高理论比容量等优点，被视为一种极具潜力的正极材料.但在传统摇椅式离子嵌入反应电池中，多价阳离子嵌入困难且易破坏MnO₂晶格结构，进而导致电池循环性能变差；同时传统电池电极制备流程复杂，阻碍了其大规模应用.基于MnO₂溶解/沉积反应的水系电池具有高理论比容量(616 mAh/g)和较高的理论电位(1.991V vs Zn/Zn2+),且无需提前制备电极即可使用等优势，成为新型水系电池的代表并备受关注.系统综述了MnO₂基水系电池的反应机理和最新研究进展，并针对存在问题分析了已提出的改性策略，同时阐述了影响电荷储能机理的相关研究.最后对基于Mn2+/MnO₂沉积/溶解化学的水系电池未来发展方向进行了展望，可为高性能水系电池的制备提供思路.

Abstract：

As one of the key components in batteries,MnO₂ is considered a promising cathode material due to its advantages such as low cost,high safety,and high theoretical specific capacity.However,in the traditional rocking chair ion embedding reaction battery,multivalent cation intercalation is difficult and tends to destroy the lattice structure of MnO₂,which leads to poor battery cycling performance.At the same time,the preparation of traditional battery electrodes is complex,which hinders its large-scale application.Batteries based on MnO₂ dissolution/deposition reaction have obvious advantages such as high theoretical specific capacity(616 mAh/g),high theoretical potential(1.991 V vs Zn/Zn2+),and practicability without the need to prepare electrodes in advance.The reaction mechanisms and the latest research progress of MnO₂-based aqueous batteries are systematically reviewed,in which the existing modification strategies are analyzed for the existing problems,and the research on the mechanism affecting charge energy storage is expounded.Finally,the future development of aqueous batteries based on Mn²+/MnO₂ deposition/dissolution chemistry is prospected,which provides ideas for the preparation of aqueous batteries with excellent performance.

关键词

关键词： 二氧化锰；溶解/沉积；水系电池；改性策略
Key words： manganese dioxide ; dissolution/deposition ; aqueous battery ; modification strategy

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