期刊信息

  • 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
  • 主办： 河北师范大学
  • ISSN： 1000-5854
  • CN： 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

协同采编系统

友情链接

基于N-乙酰-L-苯丙氨酸的Zn(Ⅱ)和Pb(Ⅱ)手性配合物的合成、晶体结构及荧光性质

  • （河北师范大学 化学与材料科学学院,石家庄 050024）
  • DOI： 10.13763/j.cnki.jhebnu.nse.202503009

Synthesis,Crystal Structures and Fluorescence Properties of Zn(Ⅱ) and Pb(Ⅱ) Chiral Complexes Based on N-acetyl-L-phenylalanine

摘要/Abstract

摘要：

以N-乙酰-L-苯丙氨酸（L-Hacphe）为主配体,合成了2种手性配合物{[Zn2(L-acphe)4(bpe)3]·2H2O·bpe}n(1)(bpe=1,2-双(4-吡啶基)乙烷)和[Pb(L-acphe)(4,4′-bipy)(NO3)]n(2)(bipy=联吡啶）,通过多种表征手段对其结构进行了分析,还研究了其固体荧光性质及对不同金属离子的荧光识别能力.结果表明:配合物1属于单斜晶系,C2手性空间群,具有一维(1D)波浪链状结构；配合物2属于单斜晶系,P21手性空间群,具有二维(2D)层状结构；2种配合物均对水溶液中的Fe3+具有良好的识别能力.

Abstract：

Two chiral complexes {[Zn2(L-acphe)4(bpe)3]·2H2O·bpe}n(1)(bpe=1,2-bis(4-pyridyl)ethane） and [Pb(L-acphe)(4,4′-bipy)(NO3)]n(2)(bipy=bipyridine) were synthesized with N-acetyl-L-phenylalanine(L-Hacphe) as main ligand.The structures of two complexes were analyzed by various characterization methods.Their solid-state fluorescence properties and fluorescence recognition ability for different metal ions were also investigated.The results showed that complex 1 belongs to the monoclinic crystal system with the C2 chiral space group,and exhibits a one-dimensional(1D) wavy chain structure.The complex 2 belongs to the monoclinic crystal system,with the P21 chiral space group,and features a two-dimensional(2D) layered structure.Both complexes showed good recognition ability for Fe3+ in aqueous solution.

关键词

关键词： 手性配合物； N-乙酰-L-苯丙氨酸； 晶体结构； 荧光识别
Key words： chiral complex ; N-acetyl-L-phenylalanine ; crystal structure ; fluorescent recognition

参考文献 25

  • [1] SUN Z,YANG M,MA Y,et al.Multi-responsive Luminescent Sensors Based on Two-dimensional Lanthanide-metal Organic Frameworks for Highly Selective and Sensitive Detection of Cr(Ⅲ) and Cr(Ⅵ) Ions and Benzaldehyde[J].Crystal Growth & Design,2017,17(8):4326-4335.doi:10.1021/acs.cgd.7b00638
  • [2] 李思浓,赵美红,宋会花.基于D(-)/L(+)-对羟基苯甘氨酸配体的镉配合物的合成、结构及荧光识别性能[J].河北师范大学学报(自然科学版),2022,46(3):282-291.doi:10.13763/j.cnki.jhebnu.nse.202203011 LI Sinong,ZHAO Meihong,SONG Huihua.Synthesis,Structure and Fluorescence Recognition Performance of Cadmium Coordination Compounds Based on D(-)/L(+)-4-hydroxyphenylglycine Ligand[J].Journal of Hebei Normal University(Natural Science),2022,46(3):282-291.
  • [3] SHIGETA Y,KOBAYASHI A,YOSHIDA M,et al.Stability Tuning of Vapor-adsorbed State of Vapochromic Pt(Ⅱ) Complex by Introduction of Chiral Moiety[J].Inorganic Chemistry,2019,58(11):7385-7392.doi:10.1021/acs.inorgchem.9b00533
  • [4] RIGAMONTI L,FORNI A,CARIATI E,et al.Solid-state Nonlinear Optical Properties of Mononuclear Copper(Ⅱ) Complexes with Chiral Tridentate and Tetradentate Schiff Base Ligands[J].Materials,2019,12(21):3595.doi:10.3390/ma12213595
  • [5] THOONEN S,HUA C.Chiral Detection with Coordination Polymers[J].Chemistry-An Asian Journal,2021,16(8):890-901.doi:10.1002/asia.202100039
  • [6] DAI F N,HE H Y,ZHAO X L,et al.1D Zigzag Chain vs. 1D Helical Chain:The Role of the Supramolecular Interactions on the Formation of Chiral Architecture[J].CrystEngComm,2010,12(2):337-340.doi:10.1039/b917264p
  • [7] LI Q P,JIANG X,DU S W.Solvent-dependent Assemblies,Structure Diversities and Magnetic Properties of Two Homochiral Co(Ⅱ)/Na(Ⅰ) Coordination Polymers[J].RSC Advances,2015,5(3):1785-1789.doi:10.1039/c4ra09263e
  • [8] MARTIN N P,VOLKRINGER C,FALAISE C,et al.Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers[J].Crystal Growth & Design,2016,16(3):1667-1678.doi:10.1021/acs.cgd.5b01746
  • [9] TAI X S,YOU H Y.A New 1D Chained Coordination Polymer:Synthesis,Crystal Structure,Antitumor Activity and Luminescent Property[J].Crystals,2015,5(4):608-616.doi:10.3390/cryst5040608
  • [10] WANG L H,YE Y X,ZHANG L Q,et al.A 3D-diamond-like Metal-organic Framework:Crystal Structure,Nonlinear Optical Effect and High Thermal Stability[J].Inorganic Chemistry Communications,2015,60:19-22.doi:10.1016/j.inoche.2015.07.015
  • [11] MAJER Z,BOSZE S,SZABÓ I,et al.Study of Dinuclear Rh(Ⅱ) Complexes of Phenylalanine Derivatives as Potential Anticancer Agents by Using X-ray Fluorescence and X-ray Absorption[J].Microchemical Journal,2015,120:51-57.doi:10.1016/j.microc.2015.01.002
  • [12] TAI X S,LIU L L,YIN J.Synthesis,Crystal Structure of Tetra-nuclear Macrocyclic Cu(Ⅱ) Complex Material and Its Application as Catalysts for A3 Coupling Reaction[J].Journal of Inorganic and Organometallic Polymers and Materials,2014,24:1014-1020.doi:10.1007/s10904-014-0077-1
  • [13] BAI K P,ZHOU L J,YANG G P,et al.Four New Metal-organic Frameworks Based on Diverse Metal Clusters:Syntheses,Structures,Luminescent Sensing and Dye Adsorption Properties[J].Journal of Solid State Chemistry,2020,287:121336.doi:10.1016/j.jssc.2020.121336
  • [14] LI S N,CAO M R,LI Y Q,et al.Three Pairs of Pb(Ⅱ),Cd(Ⅱ) and Cu(Ⅱ) Enantiomeric Coordination Compounds Based on D-(-)- and L-(+)-4-hydroxyphenylglycine:Synthesis,Structures and Properties[J].Journal of Molecular Structure,2022,1255:132451.doi:10.1016/j.molstruc.2022.132451
  • [15] DENG Q Y,LIU M Y,SHI Y J,et al.A Pair of Stable Zn(Ⅱ) Enantiomeric Coordination Compounds:Synthesis,Crystal Structures and Luminescent Recognition Properties[J].Journal of Molecular Structure,2019,1204:127530.doi:10.1016/j.molstruc.2019.127530
  • [16] LIU M Y,SHI Y J,WANG L Z,et al.Syntheses,Crystal Structures and Electrochemical Properties of Two Chiral Cu Complexes Based on D(-)/L(+)-4-hydroxyphenylglycine[J].Chinese Journal of Inorganic Chemistry,2019,35(6):1065-1075.doi:10.11862/cjic.2019.130
  • [17] HE R,SONG H H,WU L L,et al.Synthesis and Characterization of Two New Chiral Copper(Ⅱ) Compounds Constructed from (+)-N-tosyl-L-glutamic Acid[J].Chinese Journal of Chemistry,2011,29(5):898-904.doi:10.1002/cjoc.201190186
  • [18] XIN L Y,LIU G Z,MA L F,et al.Guest Water-controlled Reversible Crystalline-to-amorphous Transition and Concomitant Fluorescence Shift in a Polar Open Coordination Polymer[J].Inorganica Chimica Acta,2016,443:64-68.doi:10.1016/j.ica.2015.12.022
  • [19] ZHANG J,HUO L Q,GAO L L,et al.Luminescent and Magnetic Properties of Three Novel Metal-organic Polymers Based on a Semi-rigid Tripodal Carboxylic Ligand[J].Polyhedron,2017,137:238-245.doi:10.1016/j.poly.2017.08.015
  • [20] MIKURIYA M,INDRAWATI R,HASHIDO R,et al.Chain Compounds Based on Paddle-wheel Copper(Ⅱ) Carboxylate Bearing Four Nitroxide Radicals[J].Magnetochemistry,2018,4(2):22.doi:10.3390/magnetochemistry4020022
  • [21] GU L,ZHANG H Z,JIANG W H,et al.A Pair of Novel Zn(Ⅱ) Enantiomeric Coordination Polymers Based on a Chiral Multicarboxylate Ligand:Synthesis,Crystal Structures and Molecular Recognition Properties[J].RSC Advances,2017,7(72):45862-45868.doi:10.1039/c7ra08433a
  • [22] GUAN G X,GUO W X,LIU X,et al.Homochiral Coordination Polymers Constructed from V-shaped Oxybisbenzoyl-based Amino Acid Derivatives:Structures,Magnetic and Photoluminescence Properties[J].Dalton Transactions,2018,47(39):13990-14000.doi:10.1039/c8dt03093f
  • [23] CHANG Z,ZHANG A S,HU T L,et al.ZnⅡ Coordination Poylmers Based on 2,3,6,7-anthracenetetracarboxylic Acid:Synthesis,Structures,and Luminescence Properties[J].Crystal Growth & Design,2009,9(11):4840-4846.doi:10.1021/cg900659r
  • [24] GONG X,DING X,JIANG N,et al.Benzothiazole-based Fluorescence Chemosensors for Rapid Recognition and ″Turn-off ″ Fluorescence Detection of Fe3+ Ions in Aqueous Solution and in Living Cells[J].Microchemical Journal,2020,152:104351.doi:10.1016/j.microc.2019.104351
  • [25] CHEN S G,SHI Z Z,QIN L,et al.Two New Luminescent Cd(Ⅱ)-metal-organic Frameworks as Bifunctional Chemosensors for Detection of Cations Fe3+,Anions CrO2-4,and Cr2O2-7 in Aqueous Solution[J].Crystal Growth & Design,2017,17(1):67-72.doi:10.1021/acs.cgd.6b01197

版权所有 2013-2021 河北师范大学学报编辑部 地址：河北省石家庄市南二环东路20号

邮编：050024 电话：0311-80786360 技术支持：载驰科技