期刊信息

  • 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
  • 主办： 河北师范大学
  • ISSN： 1000-5854
  • CN： 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

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钌簇合物[6-CH3PyCH2CH(2-BrC6H4)O]2Ru3(CO)8的合成与表征

  • (河北师范大学 化学与材料科学学院,化学国家级实验教学示范中心,河北省有机功能分子重点实验室,河北 石家庄 050024)
  • DOI： 10.13763/j.cnki.jhebnu.nse.202403010

Synthesis and Characterization of Ruthenium Cluster Compound [6-CH3PyCH2CH(2-BrC6H4)O]2Ru3(CO)8

摘要/Abstract

摘要：

6-CH3PyCH2CH(2-BrC6H4)OH与Ru3(CO)12在四氢呋喃中加热回流反应,得到双配体三核钌羰基簇合物[6-CH3PyCH2CH(2-BrC6H4)O]2Ru3(CO)8.通过元素分析、红外光谱（IR）、核磁共振波谱（NMR）以及单晶X射线衍射（SXRD）对簇合物的元素组成和结构进行了表征.结果表明,簇合物分子式为C36H26Br2N2O10Ru3,属于单斜晶系,P21/c空间群，CCDC号为1907702.

Abstract：

By reacting 6-CH3PyCH2CH(2-BrC6H4)OH with Ru3(CO)12 under heating reflux in tetrahydrofuran,the dual ligand trinuclear ruthenium carbonyl cluster compound [6-CH3PyCH2CH(2-BrC6H4)O]2Ru3(CO)8 was synthesized.The elementary composition and structure of the cluster compound was characterized by elemental analysis,infrared spectrum(IR),nuclear magnetic resonance spectroscopy(NMR) and single crystal X-ray diffraction(SXRD).The results showed that the molecular formula of the cluster compound was C36H26Br2N2O10Ru3,belonging to monoclinic crystal system with space group P21/c.And the CCDC number is 1907702.

关键词

关键词： 6甲基吡啶醇 ; 羰基钌 ; 簇合物； 合成； 结构
Key words： 6-methylpyridinol ; ruthenium carbonyl ; cluster compound ; synthesis ; structure

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