期刊信息

  • 刊名: 河北师范大学学报(自然科学版)Journal of Hebei Normal University (Natural Science)
  • 主办: 河北师范大学
  • ISSN: 1000-5854
  • CN: 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

表面活性剂辅助水热合成钼酸镧钠负极材料及性能研究

  • (河北师范大学 化学与材料科学学院,河北省无机纳米材料重点实验室,河北 石家庄 050024)
  • DOI: 10.13763/j.cnki.jhebnu.nse.202403007

Performance of Sodium Lanthanum Molybdate Anode Prepared by Surfactant-assisted Hydrothermal Synthesis

摘要/Abstract

摘要:

通过表面活性剂辅助水热合成了钼酸镧钠负极材料,利用X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、循环伏安(CV)测试等对样品结构和电化学性能进行了研究.结果表明,与pH=10相比,pH=6时制备的钼酸镧钠负极材料具有更好的电化学性能,其在电流密度为0.1 A/g时,容量可达356.7 mAh/g,循环后库伦效率接近100 %.

Abstract:

The sodium lanthanum molybdate anode materials were prepared by surfactant-assisted hydrothermal synthesis.The structure and electrochemical performance of samples were investigated by X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR) and cyclic voltammetry(CV) test.The results showed that the sodium lanthanum molybdate anode material prepared at pH=6 had better electrochemical performance than that prepared at pH=10.At a current density of 0.1 A/g,its capacity could reach 356.7 mAh/g,and the coulombic efficiency after cycling was close to 100 %.

参考文献 15

  • [1] DING C S,NOHIRA T,HAGIWARA R.High capacity FeTiO3/C Negative Electrode for Sodium ion Batteries with Ultralong Cycle Life[J].J Power Sources,2018,388:19-24.doi:10.1016/j.jpowsour.2018.03.068
  • [2] KIM S W,SEO D H,MA X H,et al.Electrode Materials for Rechargeable Sodium ion Batteries:Potential Alternatives to Current Lithium-ion Batteries[J].Adv Energy Mater,2012,2(7):710-721.doi:10.1002/aenm.201200026
  • [3] VASSILARAS P,TOUMAR A J,CEDER G.Electrochemical Properties of NaNi1/3Co1/3Fe1/3O2 as a Cathode Material for Na-ion Batteries[J].Electrochem Commun,2014,38:79-81.doi:10.1016/j.elecom.2013.11.015
  • [4] PALOMARE S V,SERRAS P,VILLALUENGA I,et al.Na-ion Batteries,Recent Advances and Present Challenges to Become Low Cost Energy Storage Systems[J].Energy Environ Sci,2012,5(3):5884-5901.doi:10.1039/c2ee02781j
  • [5] LIU Y H,XU Y H,ZHU Y J,et al.Tin-coated Viral Nanoforests as Sodium ion Battery Anodes[J].ACS Nano,2013,7(4):3627-3634.doi:10.1021/nn400601y
  • [6] KOMABA S,MURATA W,ISHIKAWA T,et al.Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard carbon Electrodes and Application to Na-ion Batteries[J].Adv Funct Mater,2011,21(20):3859-3867.doi:10.1002/adfm.201100854
  • [7] CAO Y L,XIAO L F,SUSHKO M L,et al.Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications[J].Nano Lett,2012,12(7):3783-3787.doi:10.1021/nl3016957
  • [8] VALVO M,LINDGREN F,LAFONT U,et al.Towards More Sustainable Negative Electrodes in Na-ion Batteries via Nanostructured Iron Oxide[J].J Power Sources,2014,245:967-978.doi:10.1016/j.jpowsour.2013.06.159
  • [9] GAI S L,YANG G X,YANG P P,et al.Recent Advances in Functional Nanomaterials for Light-triggered Cancer Therapy[J].Nano Today,2018,19:146-187.doi:10.1016/j.nantod.2018.02.010
  • [10] TIAN Y,CHEN B J,TIAN B N,et al.Ionic Liquid assisted Hydrothermal Synthesis of Dendrite-like NaY(MoO4)2:Tb3+ Phosphor[J].Physica B Condensed Matter,2012,407(13):2556-2559.doi:10.1016/j.physb.2012.03.066
  • [11] BU W B,CHEN Z X,CHEN F,et al.Oleic Acid/oleylamine Cooperative controlled Crystallization Mechanism for Monodisperse Tetragonal Bipyramid NaLa(MoO4)2 Nanocrystals[J].J Phys Chem C,2009,113(28):12176-12185.doi:10.1021/jp901437a
  • [12] LIANG J H,PENG C,WANG X,et al.Chromate Nanorods/nanobelts:General Synthesis,Characterization,and Properties[J].Inorg Chem,2005,44(25):9405-9415.doi:10.1021/ic048237+
  • [13] YANG C Y,ZHANG L H,WANG Z,et al.Nano structured NaLa(MoO4)2 and Eu3+-doped NaLa(MoO4)2:Synthesis,Characterizations,Photoluminescence and Superhydrophobic Properties[J].Mater Sci Eng B,2016,207-39 46.doi:10.1016/j.mseb.2016.02.002
  • [14] OH S H,KIM J K,KANG Y C,et al.Three dimensionally Ordered Mesoporous Multicomponent(Ni,Mo) Metal Oxide/N-doped Carbon Composite with Superior Li ion Storage Performance[J].Nanoscale,2018,10(39):18734-18741.doi:10.1039/c8nr06727a
  • [15] JIANG Q L,DU K,CAO Y B,et al.Synthesis and Characterization of Phosphate-modified LiMn2O4 Cathode Materials for Li ion Battery[J].Chin Chem Lett,2010,21(11):1382-1386.doi:10.1016/j.cclet.2010.04.039