河北师范大学学报—

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刊名：河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
主办：河北师范大学
ISSN： 1000-5854
CN： 13-1061/N
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由芘衍生的手性单硼酸荧光探针对手性二胺类化合物的手性识别

（河北师范大学化学与材料科学学院，河北省有机功能分子重点实验室，河北石家庄 050024）
DOI： 10.13763/j.cnki.jhebnu.nse.202303013

Chiral Recognition of Pyrene-derived Chiral Monoboronic Acid Fluorescent Probes for Chiral Diamines

ZOU Jiayin，MA Ke，LI Chenfeng，LIU Meng，ZHANG Xin

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摘要/Abstract

摘要：

对由芘衍生的手性单硼酸探针R-1和S-1进行了手性二胺的对映选择性识别测试.结果表明，在L酒石酸的诱导下，R-1在2种不同溶剂体系中对手性二胺类化合物均有显著的识别能力；S-1对手性二胺类化合物也显示出一定的手性识别效果.

Abstract：

The enantioselective recognition behaviors for chiral diamines with two pyrene-derived chiral monoboronic acid fluorescent probes R-1 and S-1 in two different solvent systems were investigated.The results showed that in the presence of L tartaric acid，R-1 exhibited significant chiral recognition beha-viors for the chiral diamines in two different solvent systems,and S-1 also showed certain chiral recogni-tion effect for the chiral diamines.

关键词

关键词： 对映选择性识别；手性二胺类化合物；芘；手性荧光探针

Key words： enantioselective recognition ; chiral diamines ; pyrene ; chiral fluorescent probe

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