期刊信息

  • 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
  • 主办： 河北师范大学
  • ISSN： 1000-5854
  • CN： 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

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钛族金属-对苯二甲酸框架材料对水溶液中染料和金属离子的吸附性能

  • 河南大学 化学化工学院, 河南省多酸化学重点实验室, 河南 开封 475004
  • DOI： 10.13763/j.cnki.jhebnu.nse.202103010

ⅣB Metal-terephthalic Acid MOF for Adsorption of Dyes and Metal Ionic

摘要/Abstract

摘要：

通过溶剂热法合成了一系列高价态金属源的金属-有机框架材料（MOF）. 选取亚甲基蓝（MB）和Cr（Ⅵ）为研究对象，研究MOF-Ti，MOF-Zr，MOF-Hf对染料和金属离子的吸附效果，发现比表面积较大的Ti构筑的MOF-Ti吸附效果最优，讨论了其动力学、等温线和热力学. 通过改变吸附时间、初始浓度、pH、温度等，探究MOF-Ti对MB和Cr（Ⅵ）的吸附规律与吸附机理.

Abstract：

In this paper, a series of metal organic frameworks(MOF) containing high valence state metal ionic (MOF-Ti,MOF-Zr and MOF-Hf) were synthesized by solvent thermal method.Methylene blue (MB) and Cr(Ⅵ) were selected as the target contaminants to investigate the adsorption behavior of MOF-Ti, MOF-Zr and MOF-Hf.It was found that the adsorption capacity of MOF-Ti was the highest due to the highest specific surface area. And its kinetics,isotherm and thermodynamics were discussed. The adsorption mechanism of MOF-Ti on MB and Cr(Ⅵ) was investigated by tuning the adsorption time, initial concentration,pH and temperature , etc.

关键词

关键词： 金属-有机框架材料 ; 吸附 ; 染料 ; 金属离子
Key words： metal organic framework ; adsorbent ; dye ; metal ionic

参考文献 23

  • [1] YEOW P K,WONG S W,HADIBARATA T.Removal of Azo and Anthraquinone Dye by Plant Biomass as Adsorbent:A Review[J].Biointerface Research in Applied Chemistry,2021,11:8218-8232.doi:10.33263/briac111.82188232
  • [2] LIU F T,XIONG W J,FENG X R,et al.A Novel Monolith ZnS-ZIF-8 Adsorption Material for Ultraeffective Hg (Ⅱ) Capture from Wastewater[J].J Hazard Mater,2019,367:381-389.doi:10.1016/j.jhazmat.2018.12.098
  • [3] XIONG Y,GAO Y,GUO X R,et al. Water-stable Metal-organic Framework Material with Uncoordinated Terpyridine Site for Selective Th(Ⅳ)/Ln(Ⅲ) Separation[J].ACS Sustain Chem Eng,2019,7:3120-3126.doi:10.1021/acssuschemeng.8b04875
  • [4] 邵彩云,杨华勇,杜毅,等.金属有机框架材料用于去除环境污染物研究进展[J].化学研究,2019,30(5):537-546. SHAO Caiyun,YANG Huayong,DU Yi,et al.Recent Study on the Application of Metal-organic Frameworks Materials in the Removal of Environmental Pollutants[J].Chem Res,2019,30(5):537-546.doi:10.14002/j.hxya.2019.05.016
  • [5] KAUSHIK P,MALIK A.Process Optimization for Efficient Dye Removal by Aspergillus Lentulus FJ172995[J].J Hazard Mater,2011,185:837-843.doi:10.1016/j.jhazmat.2010.09.096
  • [6] von GUNTEN U.Oxidation Processes in Water Treatment:Are We on Track?[J]. Environ Sci Technology,2018,52:5062-5075.doi:10.1021/acs.est.8b00586
  • [7] MALTOS R A,REGNERY J,ALMARAZ N,et al. Produced Water Impact on Membrane Integrity During Extended Pilot Testing of Forward Osmosis:Reverse Osmosis Treatment[J].Desalination,2018,440:99-110.doi:10.1016/j.desal.2018.02.029
  • [8] FU J W,XIN Q Q,WU X C,et al. Selective Adsorption and Separation of Organic Dyes from Aqueous Solution on Polydopamine Microspheres[J].J Colloid Interface Sci,2016,461:292-304.doi:10.1016/j.jcis.2015.09.017.
  • [9] MEHANNA M,KIELY P D,CALL D F,et al.Microbial Electrodialysis Cell for Simultaneous Water Desalination and Hydrogen Gas Production[J].Environ Sci Technol,2010,44:9578-9583.doi:10.1021/es1025646
  • [10] KWON G,BHATNAGAR A,WANG H,et al.A Review of Recent Advancements in Utilization of Biomass and Industrial Wastes into Engineered Biochar[J].J Hazard Mater,2020,400:123242.doi:10.1016/j.jhazmat.2020.123242
  • [11] LI Z M,LIANG H W,LI X Y,et al. Adjusting Surface Acidity of Hollow Mesoporous Carbon Nanospheres for Enhanced Adsorptive Denitrogenation of Fuels[J].Chem Eng Sci,2020,228:115963.doi:10.1016/j.ces.2020.115963
  • [12] LIU M L,LI L,SUN Y X,et al. Scalable Conductive Polymer Membranes for Ultrafast Organic Pollutants Removal[J].J Membrane Sci,2021,617:118644.doi:10.1016/j.memsci.2020.118644
  • [13] BACELO H,PINTOR A M A,SANTOS S C R,et al. Performance and Prospects of Different Adsorbents for Phosphorus Uptake and Recovery from Water[J].Chem Eng J,2020,381:122566.doi:10.1016/j.cej.2019.122566
  • [14] GRANDE C A,BLOM R,MIDDELKOOP V,et al. Multiscale Investigation of Adsorption Properties of Novel 3D Printed Utsa-16 Structures[J].Chem Eng J,2020,402:126166.doi:10.1016/j.cej.2020.126166
  • [15] ZHANG C,WU B H,MA M Q,et al.Ultrathin Metal/covalent-organic Framework Membranes Towards Ultimate Separation[J].Chem Soc Rev,2019,48:3811-3841.doi:10.1039/c9cs00322c
  • [16] LI Y Z,WANG G D,YANG H Y,et al. Novel Cage-like MOF for Gas Separation,CO2 Conversion and Selective Adsorption of an Organic Dye[J].Inorg Chem Front,2020,7:746-755.doi:10.1039/c9qi01262a
  • [17] COHEN S M.Postsynthetic Methods for the Functionalization of Metal-organic Frameworks[J].Chem Rev,2012,112:970-1000.doi:10.1021/cr200179u
  • [18] DAN-HARDI M,SERRE C,FROT T,et al.A New Photoactive Crystalline Highly Porous Titanium(Ⅳ) Dicarboxylate[J].J Am Chem Soc,2009,131:10857.doi:10.1021/ja903726m
  • [19] CAVKA J H,JAKOBSEN S,OLSBYE U,et al. A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability[J].J Am Chem Soc,2008,130:13850-13851.doi:10.1021/ja8057953
  • [20] HU Z,NALAPARAJU A,PENG Y,et al.Modulated Hydrothermal Synthesis of UiO-66(Hf)-type Metal:Organic Frameworks for Optimal Carbon Dioxide Separation[J].Inorg Chem,2016,55:1134-1141.doi:10.1021/acs.inorgchem.5b02312
  • [21] BULGARIU L,RATOI M,BULGARI U,et al.The Sorption of Lead(Ⅱ) Ions from Aqueous Solutions on Peat:Kinetics Study[J].Environ Eng Manag J,2009,8:289-295.doi:10.30638/eemj.2009.041
  • [22] AHSAN M A,ISLAM M T,IMAM M A,et al. Biosorption of Bisphenol A and Sulfamethoxazole from Water Using Sulfonated Coffee Waste:Isotherm,Kinetic and Thermodynamic Studies[J].J Environ Chem Eng,2018,6:6602-6611.doi:10.1016/j.jece.2018.10.004
  • [23] PANG J Y,CHAO Y H,CHANG H H,et al. Silver Nanoparticle-decorated Boron Nitride with Tunable Electronic Properties for Enhancement of Adsorption Performance[J].ACS Sustain Chem Eng,2018,6:4948-4957.doi:10.1021/acssuschemeng.7b04481

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