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  • 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
  • 主办： 河北师范大学
  • ISSN： 1000-5854
  • CN： 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

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三重态-三重态湮灭上转换发光聚合物和超分子体系研究进展

  • 北京理工大学 材料科学与工程学院, 北京 100081
  • DOI： 10.13763/j.cnki.jhebnu.nse.202103002

Review of Triplet-triplet Annihilation Up-conversion Luminescent in Polymeric and Supramolecular System

摘要/Abstract

摘要：

上转换发光是一种通过多光子机制将低能量的光转换为高能量光的过程. 基于三重态-三重态湮灭的上转换发光所需激发光功率较低、上转化效率较高，因此自20世纪60年代以来就引起了研究人员的广泛关注；然而，由于三重激发态分子会与氧气接触而发生猝灭，一般需要在除去氧气的环境中实现上转换发光，应用范围受到了极大限制，所以研究人员设计了包含有三重态给体与受体基团的聚合物或超分子体系，利用其组装结构的致密性阻隔氧气，从而在空气气氛中实现稳定的上转换发光. 综述了近年来三重态-三重态湮灭上转换发光聚合物-超分子体系的研究进展，并探讨了该领域目前存在的问题和今后发展的方向.

Abstract：

Up-conversion luminescence is a process that converts low-energy light into high-energy light through a multi-photon mechanism,and has a wide range of applications in many fields. The up-conversion luminescence based on triplet-triplet annihilation has attracted tremendous research interests since the 1960s,because of its low excitation light power requirement and high up-conversion efficiency.Since oxygen can quench the triplet excited state of the photosensitizer,this up-conversion process is usually performed in an oxygen-free solution. Consequently,researchers have designed supramolecular or polymeric systems with triplet photosensitizer and receptor moieties incorporated,in which the close packing of molecules within the assembled structures prevent the diffusion of oxygen and thus up-conversion in air is realized. This review summarizes the recent research progress in triplet-triplet annihilation upconversion polymeric and supramolecular systems, and briefly describes the current problems in this field and the possible future directions.

关键词

关键词： 三重态-三重态湮灭 ; 上转换发光 ; 聚合物 ; 超分子
Key words： triplet-triplet annihilation ; up-conversion luminescence ; polymer ; supramolecule

参考文献 51

  • [1] JIANG Xinpeng,GUO Xinyan,MA Yuguo,et al.Triplet-triplet Annihilation Photon Upconversion in Polymer Thin Film:Sensitizer Design[J].ACS Appl Mater Interfaces,2016,8(18):11441-11449.doi:10.1021/acsami.6b01339
  • [2] ABAGAIL K W,BRAD J D,JASON D A,et al.Thiol-ene Click Chemistry:A Modular Approach to Solid-state Triplet-triplet Annihilation Upconversion[J].J Mater Chem C,2018,6(15):3876-3881.doi:10.1039/c7tc05729f
  • [3] JIANG Z,XU M,LI F,et al.Red-light-controllable Liquid-crystal Soft Actuators via Low-power Excited Upconversion Based on Triplet-triplet Annihilation[J].J Am Chem Soc,2013,135(44):16446-16453.doi:10.1021/ja406020r
  • [4] DENIZ Y,CHRISTOPH B,ROBERT G,et al.Anti-stokes Stress Sensing:Mechanochemical Activation of Triplet-triplet Annihilation Photon Upconversion[J].Angew Chem Int Ed,2019,58(37):12919-12923.doi:10.1002/anie.201907436
  • [5] SOO H L,MATHIEU A A,YOAN C S,et al.Light Upconversion by Triplet-triplet Annihilation in Diphenylanthracene-based Copolymers[J].Polym Chem,2014,5(24):6898-6904.doi:10.1039/c4py00920g
  • [6] CHRISTIAN W,ANDREY T,KATHARINA L A,et al.Annihilation Upconversion in Cells by Embedding the Dye System in Polymeric Nanocapsules Macromol[J].Biosci,2011,11(6):772-778.doi:10.1002/mabi.201000451
  • [7] WANG Weiping,LIU Qina,DANIEL S K,et al.Efficient Triplet-triplet Annihilation:Based Upconversion for Nanoparticle Phototargeting[J].Nano Lett,2015,10(6):6332-6338.doi:10.1021/acs.nanolett.5b01325
  • [8] DUAN P,CAO H,ZHANG L,et al.Gelation Induced Supramolecular Chirality:Chirality Transfer,Amplification and Application[J].Soft Matter,2014,10(30):5428-5448.doi:10.1039/c4sm00507d
  • [9] DUAN P,LI Y,JIANG J,et al.Towards a Universal Organogelator:A General Mixing Approach to Fabricate Various Organic Compounds into Organogels Sci[J].China Chem,2011,54(7):1051-1063.doi:10.1007/s11426-011-4295-x
  • [10] LIU M,ZHANG L,WANG T.Supramolecular Chirality in Self-assembled Systems[J].Chem Rev,2015,115(15):7304-7397.doi:10.1021/cr500671p
  • [11] ERIC B,EMILIE M,NICOLAS G,et al.Supramolecular Self-assemblies as Functional Nanomaterials[J].Nanoscale,2013,5(16):7098-7140.doi:10.1039/c3nr02176a
  • [12] BABATUNDE O O,WU Yuanhao,ALVARO M.Supramolecular Self-assembly to Control Structural and Biological Properties of Multicomponent Hydrogels[J].Chem Mater,2019,31(19):7883-7897.doi:10.1021/acs.chemmater.9b01882
  • [13] SAMUEL I S.On Supramolecular Self-assembly:Interview with Samuel Stupp[J].Adv Mater,2020,32(20):1906741.doi:10.1002/adma.201906741
  • [14] DUAN Pengfei,DEEPAK A,NOBUO K,et al.All-or-none Switching of Photon Upconversion in Self-assembled Organogel Systems[J].Faraday Discuss,2017,196:305-316.doi:10.1039/c6fd00170j
  • [15] PANKAJ B,SHOTA H,NOBUO K,et al.Simple and Versatile Platform for Air-tolerant Photon Upconverting Hydrogels by Biopolymer-surfactant-chromophore Co-assembly[J].J Am Chem Soc,2018,140(34):10848-10855.doi:10.1021/jacs.8b05821
  • [16] DUAN Pengfei,NOBUHIRO Y,NOBUO K,et al.Aggregation-induced Photon Upconversion Through Control of the Triplet Energy Landscapes of the Solution and Solid States[J].Angew Chem Int Ed,2015,54(26):7544-7549.doi:10.1002/anie.201501449
  • [17] TAKU O,ANGELO M,NOBUO K,et al.Highly Efficient Photon Upconversion in Self-assembled Light-harvesting Molecular Systems[J].Scientific Reports,2015,5:10882.doi:10.1038/srep10882
  • [18] ROBERTO V,ANGELO M,CHRISTOPH W,et al.Nanodrople-containing Polymers for Efficient Low-power Light Upconversion[J].Adv Mater,2017,29(41):1702992.doi:10.1002/adma.201702992
  • [19] EIJI Y,KIYOTAKA I,HAJIME I,et al.Anomalous Reactivity of Silylborane:Transition-metal-free Boryl Substitution of Aryl,Alkenyl and Alkyl Halides with Silylborane/alkoxy Base Systems[J].J Am Chem Soc,2012,134(49):19997-20000.doi:10.1021/ja309578k
  • [20] CHEN G Y,QIU H L,PRASAD P N,et al.Upconversion Nanoparticles:Design,Nanochemistry and Applications in Theranostics[J].Chem Rev,2014,114(10):5161-5214.doi:10.1021/cr400425h
  • [21] 范鸿川,杨东,段鹏飞.超分子组装体系中基于三重态-三重态湮灭的上转换发光[J].化学进展,2018,30(7):879-887.doi:10.7536/pc180222 FAN Hongchuan,YANG Dong,DUAN Pengfei.Triplet-triplet Annihilation-based Upconversion in Supramolecular System[J].Progress in Chemistry,2108,30(7):879-887.
  • [22] LIU Qian,YIN Baoru,LI Fuyou,et al.A General Strategy for Biocompatible,High-effective Upconversion Nanocapsules Based on Triplet-triplet Annihilation[J].J Am Chem Soc,2013,135(13):5029-5037.doi:10.1021/ja3104268
  • [23] WILD J,de MEIJERINK A,van SARK W G J H M,et al.Upconverter Solar Cells:Materials and Applications[J].Environ Sci,2011,12(4):4835-4848.doi:10.1039/c1ee01659h
  • [24] LI T G,LIU S W,WANG P,et al.Ultraviolet Upconversion Luminescence in Y2O3:Yb3+,Tm3+ Nanocrystals and Its Application in Photocatalysis[J].J Mater Sci,2011,46:2882-2886.doi:10.1007/s10853-010-5162-4
  • [25] KHAN A F,RAVISHANKER Y,MUKHOPADHYA P K,et al.Core-shell Nanophosphor with Enhanced NIR-visible Upconversion as Spectrum Modifier for Enhancement of Solar Cell Efficiency[J].J Nanopart Res,2011,13:6837-6846.doi:10.1007/s11051-011-0591-9
  • [26] LI Z Q,LI X D,LIU Q Q,et al.Core/shell Structured NaYF4:Yb3+/Er3+/Gd3+ Nanorods with Au Nanoparticles or Shells for Flexible Amorphous Silicon Solar Cells[J].Nanotechnology,2012,23:025402.doi:10.1088/0957-4484/23/2/025402
  • [27] HAASE M,SCHÄFER H.Upconverting Nanoparticles[J].Angew Chem Int Ed,2011,50(26):5808-5829.doi:10.1002/anie.201005159
  • [28] HUA Dawei,ZHAO Xian,XU Guibao,et al.Fluorescence Upconversion Properties of a Class of Improved Pyridinium Dyes Induced by Two-photon Absorption[J].Opt Laser Technol,2007,39(4):690-695.doi:10.1016/j.optlastec.2006.04.003
  • [29] NIU Wenbin,WU Suli,ZHANG Shufen,et al.Synthesis of Colour Tunable Lanthanide-ion Doped NaYF4 Upconversion Nanoparticles by Controlling Temperature[J].Chem Commun,2010,22(46):3908-3910.doi:10.1039/c002615h
  • [30] ETCHART I,BÉRARD M,LAROCHE M,et al.Efficient White Light Emission by Upconversion in Yb3+-,Er3+- and Tm3+-doped Y2BaZnO5[J].Chem Commun,2011,47(22):6263-6265.doi:10.1039/c1cc11427a
  • [31] PRIYAM S,RAJIV P,PRAVEEN K S,et al.An Assembly and Interaction of Upconversion and Plasmonic Nanoparticles on Organometallic Nanofibers:Enhanced Multicolor Upconversion,Downshifting Emission and the Plasmonic Effect[J].Nanotechnology,2017,28:415701.doi:10.1088/1361-6528/aa8066
  • [32] YANG W,LI X,LIU X,et al.Lanthanide-doped Upconversion Materials:Emerging Applications for Photovoltaics and Photocatalysis[J].Nanotechnology,2014,25:482001.doi:10.1088/0957-4484/25/48/482001
  • [33] PARKER C A,HATCHARD C G.Delayed Fluorescence of Pyrene in Ethanol[J].Trans Faraday Soc,1963,59:284-289.doi:10.1039/tf9635900284
  • [34] AIDA T,MEIJER E W,STUPP S I.Functional Supramolecular Polymers[J].Science,2012,335(6070):813-817.doi:10.1126/science.1205962
  • [35] KIM H,SO S,EMRICK T,et al.Functional Polymers for Growth and Stabilization of CsPbBr3 Perovskite Nanoparticles[J].Chem Commun,2019,55(12):1833-1836.doi:10.1039/c8cc09343a
  • [36] DU Jianzhong,RACHEL K O'R.Advances and Challenges in Smart and Functional Polymervesicles[J].Soft Matter,2009,5(19):3544-3561.doi:10.1039/b905635a
  • [37] JEFFREY T K.Molecular Design of Functional Polymer Surfaces[J].J Polym Sci B:Polym Phys,2004,42(16):2942-2956.doi:10.1002/polb.20157
  • [38] NICOLAS G.Supramolecular Self-assemblies as Functional Nanomaterials[J].Nanoscale,2013,5(16):7098-7140.doi:10.1039/c3nr02176a
  • [39] ARRI P,GABRIELLA C,GIUSEPPE R,et al.The Halogen Bond in the Design of Functional Supramolecular Materials:Recent Advances[J].Acc Chem Res,2013,46(11):2686-2695.doi:10.1021/ar400103r
  • [40] LIM Y B,MOONA K S,LEE M.Recent Advances in Functional Supramolecular Nanostructures Assembled from Bioactive Building Blocks[J].Chem Soc Rev,2009,38(4):925-934.doi:10.1039/b809741k
  • [41] KIMIZUKA N,YANAI N,MORIKAWA M A.Photon Upconversion and Molecular Solar Energy Storage by Maximizing the Potential of Molecular Self-assembly[J].Langmuir,2016,32(47):12304-12322.doi:10.1021/acs.langmuir.6b03363
  • [42] MONGUZZI A,MEZYK J,SCOTOGNELLA F,et al.Upconversion-induced Fluorescence in Multicomponent Systems:Steady-state Excitation Power Threshold[J].Phys Rev B,2008,78(19):195112.doi:10.1103/physrevb.78.195112
  • [43] ZHAO J Z,WU W H,SUN J F,et al.Triplet Photosensitizers:From Molecular Design to Applications[J].Chem Soc Rev,2013,42(12):5323-5351.doi:10.1039/c3cs35531d
  • [44] TAKU O,NOBUHIRO Y,NOBUO K.Donor Acceptor Collector Ternary Crystalline Films for Efficient Solid-state Photon Upconversion[J].J Am Chem Soc,2018,140(28):8788-8796.doi:10.1021/jacs.8b04542
  • [45] YE Changqing,ZHOU Liwei,WANG Xiaomei,et al.Photon Upconversion:From Two-photon Absorption (TPA) to Triplet-triplet Annihilation(TTA)[J].Phys Chem Chem Phys,2016,18(16):10818-10835.doi:10.1039/c5cp07296d
  • [46] SHOTA H,NOBUHIRO Y,NOBUO K.Photon-upconverting Ionic Liquids:Effective Triplet Energy Migration in Contiguous Ionic Chromophore Arrays[J].Angew Chem Int Ed,2015,54(39):11550-10554.doi:10.1002/anie.201505168
  • [47] DUAN Pengfei,NOBUHIRO Y,NOBUO K.Photon Upconverting Liquids:Matrix-free Molecular Upconversion Systems Functioning in Air[J].J Am Chem Soc,2013,135(51):19056-19059.doi:10.1021/ja411316s
  • [48] KAZUMA M,YOICHI S,NOBUO K,et al.Stimuli-responsive Dual-color Photon Upconversion:A Singlet-to-triplet Absorption Sensitizer in a Soft Luminescent Cyclophane[J].Angew Chem Int Ed,2018,57(11):2806-2860.doi:10.1002/anie.201712644
  • [49] SHOTA H,NOBUHIRO Y,NOBUO K,et al.Two-dimensional Structural Ordering in a Chromophoric Ionic Liquid for Triplet Energy Migration-based Photon Upconversion[J].Phys Chem Chem Phys,2018,20(5):3233-3240.doi:10.1039/c7cp06266d
  • [50] NIKITA A D,JUSSI I,ALEXANDER E,et al.Efficient Photon Upconversion at Remarkably Low Annihilator Concentrations in a Liquid Polymer Matrix:When Less Is More[J].Chem Commun,2018,54(99):14029-14032.doi:10.1039/c8cc07592a
  • [51] DI Dawei,YANG Le,FRIEND H R,et al.Efficient Triplet Exciton Fusion in Molecularly Doped Polymer Light-emitting Diodes[J].Adv Mater,2017,29(13):1605987.doi:10.1002/adma.201605987

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