期刊信息
- 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
- 主办： 河北师范大学
- ISSN： 1000-5854
- CN： 13-1061/N
- 中国科技核心期刊
- 中国期刊方阵入选期刊
- 中国高校优秀科技期刊
- 华北优秀期刊
- 河北省优秀科技期刊
基于氢键构成的一例钴(Ⅱ)超分子化合物[Co(dpb)(o-bdc)H2O]·4H2O的合成及晶体结构
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1. 陕西理工大学 化学与环境科学学院, 陕西 汉中 723001;
2. 陕西省催化基础与应用重点实验室, 陕西 汉中 723001 -
DOI：10.13763/j.cnki.jhebnu.nse.2017.05.009
Synthesis,Crystal Structure of a New Supermolecule Complex[Co(dpb)(o-bdc)H2O]·4H2O by Hydrogen-bonding Interactions
摘要/Abstract
摘要：
以2，6-双（2吡嗪基）-4，4'-联吡啶为配体、邻苯二甲酸为辅助配体，水热条件下合成了单核钴配合物[Co（dpb）（o-bdc）H2O]·4H2O，并采用元素分析、红外光谱、X射线单晶衍射对此配合物进行了分析.单晶结构解析表明，配合物为单核钴单元，单核钴之间通过氢键的进一步连接形成三维超分子网络结构.
Abstract：
A cobalt complex[Co(dpb)(o-bdc)H2O]·4H2O has been hydrothermally synthesized by reacting cobalt chloride with 2,6-di(pyrazin-2-yl)-4,4'-bipyridine ligand(dpb) and o-H2 bdc auxiliary ligand under hydrothermal condition.The complex was structurally characterized by elemental analyses,IR,and TGA.X-ray diffraction analysis of single crystal shows that the complex consists of a mononuclear structure,and these mononuclear structures are further extended into 3D supramolecular structure through intermolecular hydrogen bonding interactions.
关键词
Key words：
hydrogen bonding
;
supermolecule compound
;
hydrothermal synthesis
;
crystal structure
参考文献 13
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