河北师范大学学报—

期刊信息

刊名：河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
主办：河北师范大学
ISSN： 1000-5854
CN： 13-1061/N
中国科技核心期刊
中国期刊方阵入选期刊
中国高校优秀科技期刊
华北优秀期刊
河北省优秀科技期刊

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分级结构纳米氧化锡的制备及研究进展

刘鹏¹

张艳峰¹

魏雨¹

郭晶华²

1. 河北师范大学化学与材料科学学院, 河北石家庄 050024;
2. 劳伦斯伯克利国家实验室先进光源, 加利福尼亚伯克利 94720
DOI： 10.13763/j.cnki.jhebnu.nse.2016.03.012

Progress in the Preparation of Hierarchical Structure of Nano-tin Oxide

LIU Peng¹, ZHANG Yanfeng¹, WEI Yu¹, GUO Jinghua²

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摘要/Abstract

摘要：

综述了目前水热法制备分级结构纳米氧化锡(SnO₂)材料的形貌控制方法, 阐述了制备过程中模板、添加剂、基底等对于分级结构氧化锡形貌控制的重要作用, 在归纳、总结和比较的基础上指出了制备氧化锡纳米材料有发展潜力的可控方法, 着重阐述了制备纳米氧化锡分级形貌的最新研究进展和掺杂对于其形貌和应用的影响, 并展望了氧化锡形貌可控的应用前景.

Abstract：

The current synthesized hydrothermal methods for hierarchical structure SnO₂ nanomaterials were reviewed.The effects of templates,additives,and substrate on the morphology of hierarchical structure nanostructure tin oxide were discussed.These methods in synthesizing SnO₂ were classified,analyzed and compared.The progress and doped contents in hierarchical structure SnO₂ nanomaterials have been focused and the prospect of the morphology controllable application is outlooked.

关键词

关键词： 氧化锡 ; 纳米结构 ; 形貌控制

Key words： SnO₂ ; nanostructure ; morphology controllable

参考文献 27

[1] CHEN G,WANG Z,XIA D.One-pot Synthesis of Carbon Nanotube SnO₂-Au Coaxial Nanocable for Lithium-ion Batteries with High Rate Capability[J].Chem Mater, 2008,20:6951-6956.
[2] DING S J,CHEN J S,QI G G,et al.Formation of SnO₂ Hollow Spheres Inside Silica Nanoreactors[J].Am Chem Soc,2011,133:21-23.
[3] LU G,OCOLA L E.Room-temperature Gas Sensing Basedon Electron Transfer Between Discrete Tin Oxide Nanocrystals Andmultiwalled Carbon Nanotubes[J].Adv Mater,2009,21:2487-2491.
[4] GYGER F,HUBNER M,FELDMANN C,et al.Nanoscale SnO₂ Hollow Spheres and Its Application as a Gas Sensing Material[J].U Chem Mater,2010,22:4821-4827.
[5] KAY A,TZEL G.Dye-sensitized Core-shell Nanocrystals:Improved Efficiency of Mesoporous Tin Oxide Electrodes Coated with a Thin Layer of an Insulating Oxide[J].M Chem Mater,2002,14:2930-2935.doi:10.1021/cm0115968
[6] RAMASAMY E,LEE J.Ordered Mesoporous SnO₂-based Photoanodes for High-performance Dye-sensitized Solar Cells[J].Phys Chem C,2010,114:22032-22037.
[7] LONG J,XUE W,XIE X,et al.Sn²⁺ Dopant Induced Visible-light Activity of SnO₂ Nanoparticles for H₂ Production[J].Catal Commun,2011,16:215-219.doi:10.1016/j.catcom.2011.10.002
[8] BURDA C,CHEN X,NARAYANAN R,et al.Chemistry and Properties of Nanocrystals of Different Shapes[J].A Chem ReV,2005,105(4):1025-1102.
[9] WANG Y,IANG X,XIA Y.A Solution-phase Precursor Route to Polycrystalline SnO₂ Nanowires that Can Be Used for Gassensing Under Ambient Conditions[J].Am Chem Soc,2003,125:16176-16177.
[10] KANG S H,CHOI S H,KANG M S,et al.Nanorod-based Dye-sensitized Solar Cells with Improved Charge Collection Efficiency[J].Adv Mater,2008,20:54-58.
[11] DOU X,SABBA D,MATHEW S, et al.Hydrothermal Synthesis of High Electron Mobility Zn-doped SnO₂ Nanoflowers as Photoanode Material for Efficient Dye-sensitized Solar Cells[J].S Chem Mater,2011,23:3938-3945.
[12] ROY P,BERGER S,SCHMUK P.TiO₂ Nanotubes:Synthesis and Applications[J].Angew Chem Int Ed, 2011,50:2904-2939.
[13] HAN X,JIN M,XIE S,et al.Synthesis of Tin Dioxide Octahedral Nanoparticles with Exposed High-energy {221} Facets and Enhanced Gas-sensing Properties[J].Angew Chem Int Ed,2009,48:9180-9183.
[14] 朱路平, 贾志杰.纳米氧化锡制备方法的研究进展[J].电子元件与材料, 2004(23):34-36,45.
[15] 郭玉忠, 黄瑞安, 孙加林.SnO₂溶胶系水解缩合实验研究[J].硅酸盐学报, 2001(2):157-162.
[16] WANG Z,LUAN D,BOEY F,et al.Fast Formation of SnO₂ Nanoboxes with Enhanced Lithium Storage Capability[J].Am Chem Soc,2011,133:4738-4741.
[17] 范胜华, 李海涛, 刘力虎, 等.氧化铝模板的制备及表征[J].河北师范大学学报(自然科学版), 2008, 32(6):745-748.
[18] LIN Y S,DUH J G,HUNG M H,et al.Shell-by-shell Synthesis and Applications of Carbon-coated SnO₂ Hollow Nanospheres in Lithium-ion Battery[J].Phys Chem C,2010,114:13136-13141.
[19] LOU X W,CHEN J S,CHEN P,et al.One-pot Synthesis of Carbon-coated SnO₂ Nano-colloids with Improved Reversible Lithium Storage Properties[J].A Chem Mater,2009,21:2868-2874.
[20] WANG H Z,LIANG J B,FAN H,et al.Synthesis and Gas Sensitivities of SnO₂ Nanorods and Hollow Microspheres[J].Solid State Chem,2008,181:122-129.
[21] YAN W W,FANG M,TAN X L,et al.Template-free Fabrication of SnO₂ Hollow Spheres with Photoluminescence from Sn_<em>i[J].Mater Lett,2010,64:2033-2035.
[22] DU Ning,ZHANG Hui,CHEN Juner,et al.Metal Oxide and Sulfide Hollow Spheres:Layer-by-layer Synthesis and Their Application in Lithium-ion Battery[J].Phys Chem B,2008,112:14836-14842.
[23] 黄萍, 裴素华, 孙海波, 等.添加剂对TiO₂基敏感材料特性的影响[J].河北师范大学学报(自然科学版), 2005, 29(4):369-371.
[24] SUN P,YOU L,SUN Y,et al.Novel Zn-doped SnO₂ Hierarchical Architectures:Synthesis,Characterization and Gas Sensing Properties[J].Cryst Eng Comm,2012,14:1701-1708.
[25] YANG Rong, GUA Yingan, LI Yaoqi, et al.Self-assembled 3-D Flower-shaped SnO₂ Nanostructures with Improved Electrochemical Performance for Lithium Storage[J].Acta Mater,2010,58:866-874.
[26] WANG H,YANG H,HE L,et al.Hierarchical Growth of SnO₂ Nanostructuredfilms on FTO Substrates:Structural Defects Induced by Sn(II) Self-doping and Their Effects on Optical and Photoelectrochemical Properties[J].Nanoscale,2013,6(11):6084-6091.doi:10.1039/e4nr00672k
[27] 杨伟光,王亚丽, 史伟民,等.SnO₂纳米柱状阵列的微波水热法合成及表征[J].铜业工程, 2012(1):8-11.doi:10.3969/j.issn.1009-3842.2012.01.003