河北师范大学学报—

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刊名：河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
主办：河北师范大学
ISSN： 1000-5854
CN： 13-1061/N
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苄氧基葫芦[6]脲的合成及其结构表征

李涛¹

胡青大²

唐冬宝³

任冬雪¹

王茜¹

周运友⁴

1. 北京中医药大学东方学院中药系, 河北廊坊 065000;
2. 富士康精密电子工业有限公司冲模开发, 河北廊坊 065000;
3. 江苏省宿迁市泗洪县安监局, 江苏宿迁 223800;
4. 安徽师范大学化学与材料科学学院, 安徽芜湖 241000
DOI： 10.13763/j.cnki.jhebnu.nse.2015.05.011

Synthesis and Structural Characterization of Benzyloxycucurbit[6]uril

LI Tao¹, HU Qingda², TANG Dongbao³, REN Dongxue¹, WANG Qian¹, ZHOU Yunyou⁴

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摘要/Abstract

摘要：

以葫芦[6]脲与过二硫酸钾合成了羟基葫芦[6]脲,以氢化钠、二甲基亚砜与羟基葫芦[6]脲为原料,反应得到烷基化衍生物;将氯化苄加入此溶液中,在室温下反应合成了新型的化合物苄氧基葫芦[6]脲.其结构经荧光光谱图、紫外光谱图、红外谱图、核磁共振谱图以及质谱图分析得到了确证.

Abstract：

The perhydroxycucurbit[6]uril was synthesized by reacting cucurbit[6]uril with potassium persulfate.Then,was obtained by adding benzyl chloride to the above solution at room temperature.The alkylatedderivative was prepared from sodium hydride,methyl sulfoxide and perhydroxycucurbit[6]uril.The new compound was characterized with fluorescence spectra,UV,IR,¹H NMR and MS.

关键词

关键词： 葫芦脲 ; 羟基葫芦[6]脲 ; 氯化苄 ; 苄氧基葫芦[6]脲 ; 合成 ; 结构表征

Key words： cucurbituril ; perhydroxycucurbit[6]uril ; benzyl chloride ; benzyloxycucurbit[6]uril ; synthesis ; structural characterization

参考文献 17

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