期刊信息

  • 刊名： 河北师范大学学报（自然科学版）Journal of Hebei Normal University (Natural Science)
  • 主办： 河北师范大学
  • ISSN： 1000-5854
  • CN： 13-1061/N
  • 中国科技核心期刊
  • 中国期刊方阵入选期刊
  • 中国高校优秀科技期刊
  • 华北优秀期刊
  • 河北省优秀科技期刊

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二重穿插配位聚合物[Zn2(1,3-bip)2(bpdc)2·DMF]n的溶剂热合成、晶体结构及荧光性能研究

  • 1. 西安科技大学 能源学院, 陕西 西安 710054;
    2. 西部矿井开采及灾害防治教育部重点实验室, 陕西 西安 710054
  • DOI： 10.13763/j.cnki.jhebnu.nse.2016.04.008

Synthesis Crystal Structure and Luminescent Properties of a Novel Two-fold Interpenetrating Coordination Polymer [Zn2(1,3-bip)2(bpdc)2·DMF]n

摘要/Abstract

摘要：

以1,3二咪唑丙烷(1,3 bip),4,4'联苯二甲酸(H2bpdc)和Zn(NO3)2·6H2O为原料,在溶剂热条件下合成了二重穿插配位聚合物[Zn2(1,3-bip)2(bpdc)2·DMF]n,并采用元素分析、粉末XRD、红外光谱、X射线单晶衍射对配位聚合物的结构进行表征.结构解析结果表明,Zn(Ⅱ)作为一个四连接的节点,通过配体1,3 bip,H2bpdc连接形成一个二维(4,4)平面,相邻的2个(4,4)平面相互穿插形成一个新颖二维二重穿插的构型.另外,固体室温荧光测试结果表明,配位聚合物在330nm的光激发下于414nm处出现强烈的荧光发射峰.

Abstract：

The complex [Zn2(1,3-bip)2(bpdc)2·DMF]n was synthesized from 1,3-bis(imidazolyl)propane(1,3-bip),biphenyl-4,4'-dicarboxylic acid(H2bpdc) and zinc nitrate hexahydrate by solvothermal method and characterized by elemental analysis,IR,XRD,X-ray single crystal diffraction analysis.The results reveal that the tiltle coordination polymer features a 2D (4,4)net.In addition,the photoluminescence property of complex and 1,3-bip in the solid state at room temperature were also investigated.Upon excitation at 330nm,the maxima of emission peaks of complex was observed at 414nm.

关键词

关键词： 配位聚合物 ; 溶剂热 ; 晶体结构 ; 荧光性能
Key words： coordination polymer ; solvothermal ; crystal structure ; luminescent properties

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