在线阅读 --自然科学版 2001年4期《过渡金属卤化物和羧酸盐簇合物的键价计算与分析》
过渡金属卤化物和羧酸盐簇合物的键价计算与分析--[在线阅读]
吴育飞1, 吴建军2, 史平乐2, 戚秀菊2, 阎江敏3, 董兰4
1. 河北师范大学 化学学院, 河北 石家庄 050016;
2. 石家庄师范专科学校 化学系, 河北 石家庄 050801;
3. 石家庄市第 25中学, 河北 石家庄 050016;
4. 河北交通学校, 河北 石家庄 050095
起止页码: 493--495页
DOI:
摘要
运用原子簇化合物键价计算公式,对过渡金属卤素和氧簇合物成键情况进行了分析.这类簇合物既可以形成MM多重键,又具有空轨道,可增加σ配体,其价轨道总数与金属键数目成线性关系

Calculation and Analysis of Bond Valence of Transition Metallic Halide and Car-boxylate Cluster Compounds
WU Yu fei1, WU Jian jun2, SHI Ping le2, QI Xiu ju2, YAN Jiang min3, DONG Lan4
1. College of Chemistry, Hebei No rmal Univ ersity, Hebei, Shijiazhuang 050016, China;
2. Department of Chemistry, Shijiazhuang No rmal College, Hebei, Shijiazhuang 050801, China;
3. The 25th Middle School of Shijiazhuang, Hebei, Shijiazhuang 050011, China;
4. Hebei T raffic School, Hebei, Shijiazhuang 050095, China
Abstract:
The formation situation of the bond for transition metallic halide and carboxylate Clus-ter compounds is analysed with the bond vanlence formula for atomic cluster compounds. This category cluster compounds not only formed M— M multiple bonds, but also had empty orbits. The σligends can be addeing. The total of VBMO and the number of metal bonding MO is linear.

收稿日期: 2000-12-17
基金项目:

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