在线阅读 --自然科学版 2004年5期《氯代苯基卟啉-氨基酸及锌配合物的合成和光谱性质》
氯代苯基卟啉-氨基酸及锌配合物的合成和光谱性质--[在线阅读]
吴银素, 刘彦钦, 韩士田
河北师范大学化学学院, 河北石家庄 050016
起止页码: 496--499页
DOI:
摘要
为了探索氯的空间位置及不同的氨基酸对卟啉-氨基酸化合物性能的影响,合成了氯代苯基酪氨酸卟啉化合物和氯代苯基组氨酸卟啉化合物等6种新型的尾式卟啉-氨基酸化合物及其锌配合物,用元素分析、紫外-可见光谱确证了其结构,并研究了氯代苯基在苯环上的不同位置时卟啉化合物光谱性质的变化.

Synthesis and Spectral Properties of Chlorophenylporphyrins Amino-acid and Their Zinc Complexes
WU Yin-su, LIU Yan-qin, HAN Shi-tian
College of Chemistry, Hebei Normal University, Hebei Shijiazhuang 050016, China
Abstract:
In order to research the influence of different positions of chloro and the difference of amino acid on the porphyrin's properties,six new tailed-porphyrin compounds were synthesized:5-[4-(3-tyrosineylpororoxy)pheny]-10,15,20-tri(2,3 and 4 chlorphenyl) porphyrins and 5-[4-(3-histidineylproroxy)phenyl]-10,15,20-tri(2,3 and 4 chlorphenyl) porphyrins and their zinc complexes.Their structures were characterized by UV-VIS.In addition,the change of these compounds' spectral properties were studied.

收稿日期: 2003-9-25
基金项目: 河北省自然科学基金资助项目(203147)

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