在线阅读 --自然科学版 1999年2期《Cu(C9H6O5N2)H2O配合物的合成及热分解非等温动力学的研究》
Cu(C9H6O5N2)H2O配合物的合成及热分解非等温动力学的研究--[在线阅读]
石凤, 王大庆
山东师范大学分析测试中心, 山东济南 250014
起止页码: 241--245页
DOI:
摘要
合成了5-硝基水杨醛缩甘氨酸Cu(Ⅱ)配合物, 用元素分析、红外光谱、摩尔电导对该配合物进行了表征.并用热重(TG)对其热分解机理进行了研究, 运用Achar法和Coats-Redfern法, 推断出该配合物第三步热分解的非等温动力学方程

Synthesis and Studies on the Non-isothermal Kinetics of Thermal Decomposition Complex of Cu(C9H6O5N2)H2O
SHI Feng, WANG Da-qing
Center of Analysis, Shandong Teachers University, Jinan 250014, China
Abstract:
The complex Cu ( C9 H6O5N2 ) · H2O was prepared. Its structure was assigned on the basis of element anylysis, IR, moler conductauce. And its kinetics of thermal decomposition was studied under non-isothermlcondition with TG. The possible equation of non-isthermal kinetics at third step is suggested by the Achar method and the coats-redfern method.

收稿日期: 1998-10-23
基金项目: 国家自然科学基金资助课题( 3977076)

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