在线阅读 --自然科学版 2009年1期《新的二茂铁基氮杂环丙醇类手性配体的合成及结构表征》
新的二茂铁基氮杂环丙醇类手性配体的合成及结构表征--[在线阅读]
王倩1, 侯学会2, 王敏灿3
1. 河南广播电视大学农医学院, 河南郑州450008;
2. 郑州牧业工程高等专科学校质量与检测系, 河南郑州450011;
3. 郑州大学化学系, 河南郑州450052
起止页码: 62--69页
DOI:
摘要
合成了10种具有C2对称轴的二茂铁基氮杂环丙醇类手性配体9a~j.通过红外光谱、核磁共振氢谱等手段对其结构进行了鉴定,测定了化合物9j的晶体结构,从晶体结构可以看出手性配体9j分子内存在着一个C2对称轴.

Adsorptive Voltammetric Behavior of Gatifloxacin and Its Application
WANG Qian1, HOU Xue-hui2, WANG Min-can3
1. College of Agriculture and Medicine, Henan Radio and TV University, Henan Zhengzhou 450008, China;
2. Department of Quality Inspection and Management, Zhengzhou College of Animal Husbandry Engineering, Henan Zhengzhou 450011, China;
3. Department of Chemistry, Zhengzhou University, Henan Zhengzhou 450052, China
Abstract:
Ten novel chiral C2-asymmetric 1,1'-disubstituted ferrocenyl aziridino alcohol ligands 9a~j were synthesized and characterized by IR,1H NMR respectively.The structure of compounds 9j was further confirmed by X-ray diffraction.The crystal structure of compounds 9j revealed that a C2-symmetric chiral axis existed in the crystalline state.

收稿日期: 2008-4-30
基金项目: 国家自然科学基金(20172047)

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