在线阅读 --自然科学版 2015年4期《二嗪衍生物与羰基钌的反应研究》
二嗪衍生物与羰基钌的反应研究--[在线阅读]
韩亚雪1, 马志宏2, 商成喜3, 韩占刚1, 郑学忠1, 林进1
1. 河北师范大学 化学与材料科学学院, 河北 石家庄 050024;
2. 河北医科大学 基础医学院, 河北 石家庄 050017;
3. 承德护理职业学院 涉外护理系, 河北 承德 067000
起止页码: 333--338页
DOI: 10.13763/j.cnki.jhebnu.nse.2015.04.010
摘要
将2 氯吡嗪和2 氯嘧啶分别与Ru3(CO)12 在四氢呋喃中加热回流,得到了2个新的分子式为C14H2N2O10ClRu3的三核簇合物 1和2.通过元素分析、红外光谱、核磁共振氢谱对簇合物的结构进行了表征,并用X射线单晶衍射法测定了簇合物 1 的结构.结果表明:晶体属于三斜晶系,Pī 空间群,其晶胞参数a=0.95218(2)nm,b=1.38973(4)nm,c=1.58736(5)nm,α=79.011(2)°,β=87.709(2)°,γ=73.011(2)°,V=1.97174(9)nm3,Z=4,Dc=2.347g/cm3,μ=2.460mm-1,F(000)=1316,R1=0.0295,wR2=0.0632.CCDC:969368.

Study on the Reactions of Two Diazine Derivatives with Ruthenium Carbonyl
HAN Yaxue1, MA Zhihong2, SHANG Chengxi3, HAN Zhangang1, ZHENG Xuezhong1, LIN Jin1
1. College of Chemistry and Material Sciences, Hebei Normal University, Hebei Shijiazhuang 050024, China;
2. College of Basic Medicine, Hebei Medical University, Hebei Shijiazhuang 050017, China;
3. Department of Foreign-related Nursing, Chengde Nursing Vocational College, Hebei Chengde 067000, China
Abstract:
The 2-chloropyrazine and 2-chloropyrimidine reacted with Ru3(CO)12 in refluxing THF to give two new trinuclear cluster compounds C14H2N2O10ClRu3 1 and 2,respectively.The two new cluster compounds were characterized by IR,elemental analysis and 1HNMR spectra.The crystal structure of cluster compound 1 was determined by X-ray single crystal diffraction.Crystal data:triclinic system,space group Pī,a=0.95218(2)nm,b=1.38973(4)nm,c=1.58736(5)nm.α=79.011(2)°,β=87.709(2)°,γ=73.011(2)°,V=1.97174(9)nm3,Z=4,Dc=2.347g/cm3,μ=2.460mm-1,F(000)=1316,R1=0.0295,wR2 =0.0632.CCDC:969368.

收稿日期: 2014-9-16
基金项目: 国家自然科学基金(21372061); 河北省自然科学基金(B2013205025,B2014205018); 河北师范大学重点基金(L2012Z02)

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